N-Trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline ozonides

被引:0
|
作者
A. G. Tolstikov
R. G. Savchenko
D. V. Nedopekin
S. R. Afon’kina
E. S. Lukina
V. N. Odinokov
机构
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源
Russian Chemical Bulletin | 2011年 / 60卷
关键词
cycloaddition; cyclopentadiene; imines; 3a,4,5,9b-tetrahydro-3; -cyclo-penta[; ]quinolines; trifluoroacetamides; ozonolysis; ozonides; the Povarov reaction;
D O I
暂无
中图分类号
学科分类号
摘要
A three-component condensation of aromatic amine, aldehyde, and cyclopentadiene with subsequent N-trifluoroacetylation leads to 4- and 4,8-substituted N-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinolines. Ozonation of the double bond in the latter produced the corresponding isomeric stable ozonides having (1R*,4S*,5aR*,6S*,11bR*)-configuration and differing in inversion at the carboxamide nitrogen atom.
引用
收藏
页码:160 / 167
页数:7
相关论文
共 50 条