Study on biodegradability of poly(amide-imide)s containing N-trimellitylimido-L-amino acids and 3,5-diamino-N-(pyridin-3-yl)benzamide linkages

被引：0

作者：

S. Mallakpour

H. Ayatollahi

M. R. Sabzalian

机构：

[1] Isfahan University of Technology,Organic Polymer Chemistry Research Laboratory, Department of Chemistry

[2] Isfahan University of Technology,Nanotechnology and Advanced Materials Institute

[3] Isfahan University of Technology,Center of Excellence in Sensors and Green Chemistry, Department of Chemistry

[4] Isfahan University of Technology,College of Agriculture, Department of Agronomy and Plant Breeding

来源：

Polymer Science Series B | 2014年 / 56卷

关键词：

Polymer Science Series; Benzamide; TBAB; Direct Polycondensation; Triphenyl Phosphite;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A series of novel biodegradable functional amino acid-based poly(amide-imide)s (PAI)s were designed and synthesized by the direct polycondensation reaction of chiral bioactive diacids composed of naturally occurring α-amino acids with 3,5-diamino-N-(pyridin-3-yl) benzamide in the presence of molten tetrabutylammonium bromide as a green solvent. These new biodegradable polymers were characterized with Fourier transfer infrared and 1H NMR spectroscopy, field emission scanning electron microscopy. In addition, in vitro toxicity and biodegradability behavior of the starting diacids, diamine and obtained PAIs were investigated in culture media and the results showed that the synthesized monomers and their derived polymers are biologically active and their degradation products are probably nontoxic to microbial growth.

引用

页码：464 / 470

页数：6

共 46 条

[41] New optically active poly(amide-imide)s from N,N'-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic)bis-l-phenyl alanine and aromatic diamines: synthesis and characterization
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[42] New optically active poly(amide-imide)s from N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracrboxylic)-bis-L-valine diacid and aromatic diamines: synthesis and properties
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[43] Preparation and Characterization of New Optically Active Poly(amide-imide)s from N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetra carboxylic)-bis-L-isoleucine and Aromatic Diamines
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[44] Synthesis and characterization of new optically active and heat resistant poly(amide-imide)s derived from N,N′-(bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic)-bis-L-leucine and aromatic diamines
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[45] New photosensitive and optically active organo-soluble poly(amide-imide)s from N,N'-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids and 1,5-bis(4-aminophenyl)penta-1,4-dien-3-one: synthesis and characterization
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[46] New photosensitive and optically active organo-soluble poly(amide–imide)s from N,N′-(bicyclo[2,2,2]oct-7-ene-tetracarboxylic)-bis-L-amino acids and 1,5-bis(4-aminophenyl)penta-1,4-dien-3-one: synthesis and characterization
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