Formation and stabilization of F centers following direct generation of self-trapped excitons in KCl crystals

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作者
I. A. Kudryavtseva
E. A. Vasil’chenko
A. Ch. Lushchik
Ch. B. Lushchik
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[1] Tartu University,Institute of Physics
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Spectroscopy; State Physics; Direct Generation; Decay Channel; Irradiation Temperature;
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摘要
The spectrum of luminescent F centers generated in high-purity KCl crystals by 7–10.2-eV photons has been measured at 230 K. The pulsed annealing of these centers (250–550 K), as well as the dependence of the efficiency of stable F-center generation on irradiation temperature (80–500 K) has been studied. The efficiencies of F− and Cl3−-center generation are maximum under direct optical creation of self-trapped excitons in the region of the Urbach intrinsicabsorption tail. Besides the exciton decay with formation of F centers and mobile H centers, a high-temperature exciton decay channel which involves creation of cation defects stabilizing the H centers has been revealed.
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页码:388 / 395
页数:7
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