Synthesis and steric structure of N″-(arylmethylidene)-N″′-(1-methyl-3-phenylprop-2-yn-1-ylidene)thiocarbonohydrazides

被引：0
|
作者：
T. E. Glotova
M. Yu. Dvorko
N. N. Chipanina
A. I. Albanov
L. V. Sherstyannikova
O. N. Kazheva
A. N. Chekhlov
O. A. D’yachenko
机构：
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
[2] Russian Academy of Sciences,Institute of Chemical Physics Problems
来源：
Russian Journal of Organic Chemistry | 2008年 / 44卷
关键词：
Aromatic Aldehyde; Benzylidene; Compound IIIa; Aqueous Acetic Acid; Steric Structure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Thiocarbonohydrazones derived from aromatic aldehydes reacted with 4-phenylbut-3-yn-2-one in aqueous acetic acid (20°C, 2 h) to produce previously unknown N″-[(E-s-cis)-arylmethylidene]-N″′-[(Z-s-trans)-1-methyl-3-phenylprop-2-yn-1-ylidene]thiocarbonohydrazides with high chemo-, regio-, and stereoselectivity. The steric structure of N″-[(E-s-cis)-benzylidene]-N″′-[(Z-s-trans)-1-methyl-3-phenylprop-2-yn-1-ylidene]thiocarbonohydrazide in crystal and in solution was studied by X-ray analysis and IR and NMR spectroscopy.
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页码：114 / 119
页数：5
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