Modelling tyrosinase monooxygenase activity. Activation of dioxygen by dicopper(I) complexes and characterisation of dicopper(II) complexes

被引：0
|
作者：
Gupta R. [1 ]
Ghosh D. [1 ]
Mukherjee R. [1 ]
机构：
[1] Department of Chemistry, Indian Institute of Technology
来源：
Journal of Chemical Sciences | 2000年 / 112卷 / 3期
关键词：
Dioxygen; dicopper complexes; -xylyl-based dinucleating ligands; stoichiometric oxidation reactions;
D O I：
10.1007/BF02706170
中图分类号：
学科分类号：
摘要：
Activation of dioxygen on dicopper(I) centres was systematically investigated using a group of open-chain and a macrocyclic m-xylyl-based dinucleating ligand from a bioinorganic viewpoint. Even though intermediate peroxo-dicopper(II) species was not detected (even at -80°C for the open-chain system), the putative intermediate reacted with C-H groups in ligands giving oxygenated products (C-OH groups). Absorption, spectroscopic and magnetic properties of the final dicopper(II) complexes have been investigated.
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页码：179 / 186
页数：7
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