One Three-Dimensional {Mn4} Cluster Coordination Polymer from a New Tetracarboxylate Linker and N-Donor Ancillary Ligand: Crystal Structure and Magnetic Property

被引：0
|
作者：
Rong-Fang Li
Xin-Fang Liu
Yu-Fang Wang
Tian Zhang
Xun Feng
机构：
[1] Luoyang Normal University,College of Chemistry and Chemical Engineering
来源：
Journal of Inorganic and Organometallic Polymers and Materials | 2015年 / 25卷
关键词：
Biphenyl-2,3,3′,5′-tetracarboxylic acid; 1,4-Bis(2-pyridylmethyl)piperazine; Manganese cluster; Magnetic property;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Hydrothermal reactions of biphenyl-2,3,3′,5′-tetracarboxylic acid (H4bptc) with manganese salt in the presence of 1,4-bis(2-pyridylmethyl)piperazine (bpmp) afforded one novel coordination polymer, namely, [Mn2(bptc)(bpmp)0.5]n (1). Its structure was established by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra and TG analysis. Complex 1 contains {Mn4} cluster, exhibiting an unusual mode of two-fold interpenetrating three-dimensional (3D) framework with a (3, 8)-connected (84.102) (4.7.84.102.11.15) topology. In addition, magnetic susceptibility measurements indicate that complex 1 show weak antiferromagnetic interactions between the adjacent manganese ions.
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页码：1200 / 1204
页数：4
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