A five-coordinate complex of copper chloride with 2-amino-5-ethyl-1,3,4-thiadiazole

被引:0
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作者
Sh. A. Kadirova
M. M. Ishankhodzhaeva
N. A. Parpiev
Z. Karimov
A. Tozhiboev
B. Tashkhodzhaev
机构
[1] Ulugbek National University of Uzbekistan,Yunusov Institute of Chemistry of Plant Substances
[2] St. Petersburg State Technological University of Plant Polymers,undefined
[3] Tashkent Institute of Irrigation and Melioration,undefined
[4] Academy of Sciences of Uzbekistan Republic,undefined
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关键词
CuCl; Uzbekistan; Thiadiazole; Outer Sphere; Copper Chloride;
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摘要
A complex of Cu(II) chloride with 2-amino-5-ethyl-1,3,4-thiadiazole (AET) was prepared, and its structure was studied by IR spectroscopy and single crystal X-ray diffraction. The complex has the composition CuCl2(AET)4. The coordination sphere of the copper atom includes four molecules of the heterocyclic ligand coordinated via N atoms of thiadiazole rings and one of Cl− anions; the second Cl− anion is in the outer sphere.
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页码:1799 / 1801
页数:2
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