A Study of Excess Molar Enthalpies and Excess Molar Volumes of Binary Mixtures of 1-Chloropentane + 1-Alkanol (from 1-Butanol to 1-Octanol) at 25°C.

被引：0

作者：

P. Santana

J. Balseiro

E. Jiménez

C. Franjo

J. L. Legido

E. Carballo

M. I. Paz Andrade

机构：

[1] Universidade de Santiago,Departamento de Física Aplicada, Campus Universitario Sur

[2] Universidade de A Coruña,Departamento de Física, Facultade de Ciencias, Campus A Zapateira

[3] Universidade de Vigo,Departamento de Física Aplicada, Facultade de Ciencias

[4] Universidade de Santiago,Departamento de Física Aplicada, Campus Universitario Sur

来源：

Journal of Solution Chemistry | 2000年 / 29卷

关键词：

excess molar enthalpies; excess molar volumes; group contribution; hydrogen bonding; steric interaction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Excess molar enthalpies HEmand excess molar volumes VEm at 25°Cand normal atmospheric pressure for the binary mixtures 1-chloropentane + 1-alkanol(from 1-butanol to 1-octanol) have been determined using a Calvet microcalorimeterand from density measurements using a vibrating tube densimeter. The HEm valuesfor all the mixtures are positive and VEm values are positive or negative dependingon the mole fraction of the chloroalkane. Experimental HEm results are comparedwith the predictions of UNIFAC group-contribution models proposed by Dang andTassios and by Larsen et al., and are discussed in terms of molecular interactions.

引用

页码：1115 / 1122

页数：7

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