On the Molar Volumes and Viscosities of Electrolytes

被引：0
|
作者：
Yizhak Marcus
机构：
[1] The Hebrew University of Jerusalem,Department of Inorganic and Analytical Chemistry
来源：
Journal of Solution Chemistry | 2006年 / 35卷
关键词：
Apparent molar volume; Aqueous electrolytes; Non-aqueous solutions; Viscosity B-coefficient;
D O I：
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学科分类号：
摘要：
The bV coefficient of the term linear with the concentration of the apparent molar volume ϕV of electrolytes in water and several non-aqueous solvents is examined. Its relationship with the Bη coefficient of the corresponding term in the relative viscosity of these electrolyte solutions is explored. Positive correlations are found in some cases as expected, but in others, where crowding of the solvation shells occurs on increasing concentration, such correlations fail.
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页码：1271 / 1286
页数：15
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