Decoupled multicomponent potential theory of adsorption of gas mixtures

被引:0
|
作者
Raphaël Gervais Lavoie
Jean Hamelin
Pierre Bénard
机构
[1] Université du Québec à Trois-Rivières,Institut de recherche sur l’hydrogène
[2] Université du Québec à Trois-Rivières,Département de chimie, biochimie et physique
来源
SN Applied Sciences | 2020年 / 2卷
关键词
Adsorption; Mixture adsorption; Multicomponent adsorption; Potential theory of adsorption; MPTA; Density functional theory;
D O I
暂无
中图分类号
学科分类号
摘要
In this paper, we present a new version of the multicomponent potential theory of adsorption model. The proposed modification makes a clear distinction between adsorbent dependent parameters from adsorbate dependent ones. This leads to a better understanding of the physical significance of the parameters. The interdependence between pure isotherms is eliminated, which means that each component can be individually finely adjusted. This new approach was tested against 14 datasets for a total of 510 experimental mixture adsorption data of CH4\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_4$$\end{document}, CO2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_2$$\end{document}, N2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_2$$\end{document}, H2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_2$$\end{document}, O2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_2$$\end{document}, H2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_2$$\end{document}S, C2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_2$$\end{document}H6\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_6$$\end{document}, C3\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_3$$\end{document}H6\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_6$$\end{document}, and C3\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_3$$\end{document}H8\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$_8$$\end{document} on activated carbons, MOF, and zeolites. A slight improvement of 4.67% on excess adsorption predictions was found, leading to an overall average error of 6.97% for total excess adsorption and 15.30% for combined mixtures and components excess adsorption predictions.
引用
收藏
相关论文
共 50 条
  • [21] Potential Theory of Adsorption for Associating Mixtures: Possibilities and Limitations
    Bjorner, Martin G.
    Shapiro, Alexander A.
    Kontogeorgis, Georgios M.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (07) : 2672 - 2684
  • [22] Multicomponent diffusion in gas mixtures
    Telyakov, E. Sh
    Nizamov, I. I.
    Tarenko, B. I.
    Bikmurzin, A. R.
    Osipova, L. E.
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2013, 47 (04) : 330 - 335
  • [23] CONDUCTANCE OF MULTICOMPONENT GAS MIXTURES
    CHERNOV, YG
    HIGH TEMPERATURE, 1970, 8 (05) : 881 - &
  • [24] MULTICOMPONENT ADSORPTION EQUILIBRIA OF NONIDEAL MIXTURES
    TALU, O
    ZWIEBEL, I
    AICHE JOURNAL, 1986, 32 (08) : 1263 - 1276
  • [25] EQUILIBRIUM IN MULTICOMPONENT GAS MIXTURES
    SPACIL, HS
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1963, 110 (08) : C186 - C187
  • [26] ADSORPTION OF MULTICOMPONENT MIXTURES BY SOLID ADSORBENTS
    GONZALEZ, AJ
    HOLLAND, CD
    AICHE JOURNAL, 1970, 16 (05) : 718 - &
  • [27] THEORY OF MULTICOMPONENT FLUID MIXTURES .3. PSEUDO PAIR POTENTIAL
    SALSBURG, ZW
    JOURNAL OF CHEMICAL PHYSICS, 1962, 36 (08): : 1974 - &
  • [28] Simulation of high-pressure sour natural gas adsorption equilibrium on NaX and NaY zeolites using the multicomponent potential theory of adsorption
    M. V. Pereira
    L. H. de Oliveira
    J. F. do Nascimento
    P. A. Arroyo
    Adsorption, 2023, 29 : 65 - 72
  • [29] Simulation of high-pressure sour natural gas adsorption equilibrium on NaX and NaY zeolites using the multicomponent potential theory of adsorption
    Pereira, M. V.
    de Oliveira, L. H.
    do Nascimento, J. F.
    Arroyo, P. A.
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2023, 29 (01): : 65 - 72
  • [30] VACANCY SOLUTION THEORY OF ADSORPTION FROM GAS-MIXTURES
    SUWANAYUEN, S
    DANNER, RP
    AICHE JOURNAL, 1980, 26 (01) : 76 - 83