Reactions of alicyclic epoxy compounds with oxygen-centered nucleophiles

被引:0
|
作者
L. I. Kas’yan
A. O. Kas’yan
S. I. Okovityi
机构
[1] Dnepropetrovsk National University,Institut für organische Chemie
[2] Rheinisch-Westfälische technische Hochschule,undefined
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关键词
Alcohol; Organic Chemistry; Epoxy; Organic Acid; Active Product;
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学科分类号
摘要
The review analyzes the reactions of alicyclic epoxy compounds with oxygen-containing nucleophiles (alcohols, water, and organic acids), describes biologically active products of these reactions, and discusses their mechanisms and results of their simulation by quantum-chemical methods. The regio-and stereoselectivity of nucleophilic reactions of epoxy compounds and the activation of epoxy ring by achiral and chiral catalysts are also considered.
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页码:307 / 337
页数:30
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