Micellar and salt effects upon the oxidation of N,N-dimethylaniline by hexacyanoferrate(III)

被引：0
|
作者：
J. K. J. Salem
H. J. Y El- Aila
机构：
[1] Al- Azhar University,Department of Chemistry
[2] Al - Aqsa University,Department of Chemistry
来源：
Reaction Kinetics and Catalysis Letters | 2003年 / 80卷
关键词：
oxidation; N; hexacyanoferrat(III); kinetic; N-dimethylaniline;
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摘要：
The oxidation of N,N-dimethylaniline (DMA) by hexacyanoferrate (III) (Fe (CN)63-) has been studied in aqueous and micellar solutions of N,N-dimethyl- dodecylamine N-oxide (DDAO). The rate enhancement of the reaction in the presence of micelles has been explained with the pseudo- phase model of the kinetics.The dependence of the reaction rate on the nature of the salt cation has also been discussed.
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页码：105 / 112
页数：7
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