Synthesis and X-Ray Crystal Structure of Two Novel Complexes: [MII(phen)3]2V4O12·phen·22H2O(MII=Co, Ni; phen=phenanthroline)

被引：0

作者：

L’udmila Žúrková

Renáta Kucsera

Róbert Gyepes

Michal Sivák

机构：

[1] Department of Inorganic Chemistry,

[2] Faculty of Natural Sciences,undefined

[3] Comenius University,undefined

[4] SK-84215,undefined

[5] Bratislava,undefined

[6] Slovak Republic,undefined

[7] Department of Inorganic Chemistry,undefined

[8] Faculty of Natural Sciences,undefined

[9] Charles University,undefined

[10] CS-12800,undefined

[11] Praha,undefined

[12] Czech Republic,undefined

来源：

Monatshefte für Chemie / Chemical Monthly | 2003年 / 134卷

关键词：

Keywords. Inorganic–organic hybrid materials; X-ray structure determination.;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Two novel compounds, [Co(phen)3]2V4O12·phen·22H2O (1) and [Ni(phen)3]2 V4O12·phen·22H2O (2), were prepared from KVO3–1,10-phenanthroline (phen)–Co(NO3)2, resp. NiCl2–H2O reaction systems. The compounds 1 and 2 are isomorphous and crystallize in triclinic system, space group P-1. Their crystal structures are formed by two types of layers parallel to 001: a cationic one consisting of [MII(phen)3]2+ ions and an anionic one containing the cyclic V4O124− anions. The solvate phenanthroline and crystal water molecules are located in the cationic and anionic layers, respectively. The IR spectra of 1 and 2 are consistent with the presence of the cyclic V4O124− anions in the complexes.

引用

页码：1071 / 1079

页数：8

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