Photolytic transformations of aluminum, gallium, and indium tris(3,6-di-tert-butyl-1,2-semiquinolates)

被引:0
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作者
E. V. Ilyakina
O. G. Mishchenko
A. V. Piskunov
S. V. Maslennikov
I. V. Spirina
Yu. A. Kurskii
A. V. Lado
机构
[1] Lobachevskii Nizhny Novgorod State University,Research Institute of Chemistry
[2] Russian Academy of Sciences,Razuvaev Institute of Organometallic Chemistry
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Gallium; Photolysis; General Chemistry; Activate Charcoal; Saturated Hydrocarbon;
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摘要
The quantum yields of photolytic transformations of aluminum, gallium, and indium tris(3,6-di-tert-butyl-1,2-semiquinolates) in solutions of saturated hydrocarbons were determined. The final products of photodecomposition formed upon irradiation of the compounds with the light of wavelength 313 nm were identified. The kinetic scheme for decomposition of the metal o-semiquinone complexes upon irradiation is suggested.
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页码:724 / 727
页数:3
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