A structural study on gallium and indium β-diketonates

被引：0
|
作者：
Subrato Bhattacharya
Sudha Singh
Vishnu D. Gupta
机构：
[1] Post Graduate College,Chemistry Department
[2] Banaras Hindu University,Department of Chemistry, Faculty of Science
来源：
Journal of Chemical Crystallography | 2002年 / 32卷
关键词：
-Diketonate; gallium(III); indium(III); 1,3-diphenylpropane-1,3-dionato; 2,2′, 6,6′-tetra-methylheptane-3,5-dionato;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In an attempt to prepare pentacoordinate chlorobis(β-diketonato) gallium(III) and indium(III) complexes only the corresponding tris-products, Ga(PhCOCHCOPh)3 (1), Ga(tBuCOCHCOtBu)3 (1a), and In(PhCOCHCOPh)3 (2), could be isolated. The crystal and molecular structures of 1 and 2 were determined. Both the complexes were found to have triclinc crystal system, with P1 space group. Cell parameters: 1 – a = 9.913(3) Å, b = 10.534(6) Å, c = 18.05(2) Å, α = 93.86(5)°, β = 94.40(4)°, γ = 106.58(4)°, V = 1805(2) Å3, z = 2; 2 – a = 10.507(3) Å, b = 11.448(3) Å, c = 16.322(4) Å, α = 107.38(2)°, β = 97.38(2)°, γ = 102.23(2)°, V = 1792(1) Å3, z = 2.
引用
收藏
页码：299 / 305
页数：6
相关论文
共 50 条
  • [31] Electrodepositied Gallium on Gallium and Copper/Indium Substrates
    Zhang Chao
    Ao Jian-Ping
    Wang Li
    Jiang Tao
    Sun Guo-Zhong
    He Qing
    Zhou Zhi-Qiang
    Sun Yun
    ACTA PHYSICO-CHIMICA SINICA, 2012, 28 (08) : 1913 - 1922
  • [32] STUDIES ON HETEROCYCLIC BETA-DIKETONATES OF INDIUM(III)
    SINGH, Y
    RAI, AK
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1984, 23 (08): : 694 - 696
  • [33] Structural and electronic properties of interstitial oxygen defect in amorphous indium gallium oxide (IGO) semiconductors: a theoretical study
    Pandy, Chitra
    Kobayashi, Masaharu
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2025, 64 (02)
  • [34] The effect of indium surfactant on the optoelectronic and structural properties of MBE grown gallium nitride
    Zhu, CF
    Fong, WK
    Leung, BH
    Cheng, CC
    Surya, C
    Sundaravel, B
    Luo, EZ
    Xu, JB
    Wilson, IH
    MORPHOLOGICAL AND COMPOSITIONAL EVOLUTION OF HETEROEPITAXIAL SEMICONDUCTOR THIN FILMS, 2000, 618 : 153 - 158
  • [35] Structural color switching with a doped indium-gallium-zinc-oxide semiconductor
    INKI KIM
    JUYOUNG YUN
    TREVON BADLOE
    HYUK PARK
    TAEWON SEO
    YOUNGHWAN YANG
    JUHOON KIM
    YOONYOUNG CHUNG
    JUNSUK RHO
    Photonics Research , 2020, (09) : 1409 - 1415
  • [36] STRUCTURAL DIFFERENCES OF DOUBLE OXIDES, FORMED BY INDIUM AND GALLIUM WITH SB-(V)
    VARFOLOMEEV, MB
    SOTNIKOVA, MN
    CHIBIROVA, FK
    SHPINEL, VS
    ZHURNAL NEORGANICHESKOI KHIMII, 1975, 20 (05): : 1163 - 1166
  • [37] Structural color switching with a doped indium-gallium-zinc-oxide semiconductor
    Kim, Inki
    Yun, Juyoung
    Badloe, Trevon
    Park, Hyuk
    Seo, Taewon
    Yang, Younghwan
    Kim, Juhoon
    Chung, Yoonyoung
    Rho, Junsuk
    PHOTONICS RESEARCH, 2020, 8 (09) : 1409 - 1415
  • [38] Synthesis and Structural Characterization of Gallium(I) and Indium(I) Cations Coordinated by Pentamethylethylenediamine
    Glootz, Kim
    Kratzert, Daniel
    Krossing, Ingo
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2020, 646 (11-12): : 523 - 525
  • [39] STRUCTURAL CHARACTERISTICS OF MELTS OF ALUMINUM, GALLIUM AND INDIUM ANTIMONIDES NEAR CRYSTALLIZATION TEMPERATURE
    GLAZOV, VM
    TIMOSHENKO, VI
    ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (09): : 2193 - 2196
  • [40] Efficient separation and purification of indium and gallium in spent Copper indium gallium diselenide (CIGS)
    Li, Xiang
    Ma, Baozhong
    Hu, Die
    Zhao, Qinqing
    Chen, Yongqiang
    Wang, Chengyan
    JOURNAL OF CLEANER PRODUCTION, 2022, 339
12345