Coordination compounds based on the cluster anion [Re4Te4(CN)12]4− and Zn2+ cation

被引：0

作者：

Yu. V. Mironov

O. A. Efremova

D. Yu. Naumov

V. E. Fedorov

机构：

[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry

[2] Novosibirsk State University,undefined

来源：

Russian Chemical Bulletin | 2006年 / 55卷

关键词：

rhenium; tetrahedral chalcocyanide clusters; zinc; cyanide bridges; coordination polymers; polydentate amines; crystal structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Three new coordination compounds [{Zn(H2O)2} {Zn(H2O)4} Re4Te4(CN)12] (1), [Zn(en)2(NH3)2][{Zn(en)(NH3)2} Re4Te4(CN)12]·H2O (2), and [{Zn2(dien)3} Re4Te4(CN)12]· ·6H2O (3) (dien is diethylenetriamine) were prepared by reactions of aqueous solutions of the tetrahedral cluster rhenium tellurocyanide complex K4[Re4Te4(CN)12]· 5H2O with zinc dichloride in the presence of ammonia, ethylenediamine, and diethylenetriamine, respectively. Complex 1 has a three-dimensional structure with two types of the Zn atoms; complex 2 is ionic with the polymeric chain anion; complex 3 has a molecular structure. The structures of complexes 1–3 were determined by single-crystal X-ray diffraction analysis.

引用

页码：744 / 747

页数：3

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