Coordination compounds based on the cluster anion [Re4Te4(CN)12]4− and Zn2+ cation

被引：0
|
作者：
Yu. V. Mironov
O. A. Efremova
D. Yu. Naumov
V. E. Fedorov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
来源：
Russian Chemical Bulletin | 2006年 / 55卷
关键词：
rhenium; tetrahedral chalcocyanide clusters; zinc; cyanide bridges; coordination polymers; polydentate amines; crystal structure;
D O I：
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学科分类号：
摘要：
Three new coordination compounds [{Zn(H2O)2} {Zn(H2O)4} Re4Te4(CN)12] (1), [Zn(en)2(NH3)2][{Zn(en)(NH3)2} Re4Te4(CN)12]·H2O (2), and [{Zn2(dien)3} Re4Te4(CN)12]· ·6H2O (3) (dien is diethylenetriamine) were prepared by reactions of aqueous solutions of the tetrahedral cluster rhenium tellurocyanide complex K4[Re4Te4(CN)12]· 5H2O with zinc dichloride in the presence of ammonia, ethylenediamine, and diethylenetriamine, respectively. Complex 1 has a three-dimensional structure with two types of the Zn atoms; complex 2 is ionic with the polymeric chain anion; complex 3 has a molecular structure. The structures of complexes 1–3 were determined by single-crystal X-ray diffraction analysis.
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页码：744 / 747
页数：3
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