This paper is concerned with a biharmonic equation under the Navier boundary condition \documentclass[12pt]{minimal}
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$${(P_{\mp\varepsilon}): \Delta^{2}u = u^{\frac{n+4}{n-4}\mp\varepsilon}}$$
\end{document} , u > 0 in Ω and u = Δu = 0 on ∂Ω, where Ω is a smooth bounded domain in \documentclass[12pt]{minimal}
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$${\mathbb{R}^n}$$
\end{document}, n ≥ 5, and ε > 0. We study the asymptotic behavior of solutions of (P−ε) which are minimizing for the Sobolev quotient as ε goes to zero. We show that such solutions concentrate around a point x0 ∈Ω as ε → 0, moreover x0 is a critical point of the Robin’s function. Conversely, we show that for any nondegenerate critical point x0 of the Robin’s function, there exist solutions of (P−ε) concentrating around x0 as ε → 0. Finally we prove that, in contrast with what happened in the subcritical equation (P−ε), the supercritical problem (P+ε) has no solutions which concentrate around a point of Ω as ε → 0.