Crystal structure of 4-methylpyridinium 2,4-dinitrophenolate

被引:0
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作者
Zhi Min Jin
Ji Zhong Yan
Ya Ping LÜ
Ling He
Nan Sun
机构
[1] Zhejiang University of Technology,College of Pharmaceutical Sciences
[2] Zhejiang University,Department of Chemistry
来源
Journal of Chemical Crystallography | 2001年 / 31卷
关键词
2,4-dinitrophenol; 4-methylpyridine; bifurcated hydrogen bonding; CHO hydrogen bond; π–π interaction;
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摘要
A crystalline salt of 4-methylpyridinium 2,4-dinitrophenolate has been prepared and characterized by X-ray crystallography. The salt crystallizes in the monoclinic space group P21/c with a = 9.105(2), b = 7.617(2), c = 18.424(3) Å, α = 90.00, β = 101.19(1), γ = 90.00°, V = 1253.5(5) Å3, and Z = 4. In the title salt, the phenolate and pyridinium ion are held by bifurcated hydrogen bonds of N–H···O, and are arranged in an almost coplanar manner to each other due to two sets of CHO hydrogen bonds. The geometrical arrangement in the title salt is characterized by the formation of herringbone motif of 4-methylpyridinium 2,4-dinitrophenolate. The herringbone motif is stablized by CHO hydrogen bonds. The face-to-face interval between the phenolate and pyridinium ring is 3.3094 Å, in a range governed by π–π interaction.
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页码:345 / 348
页数:3
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