Synthesis of several optically active menthane disulfides and thiosulfinates

被引：0

作者：

E. S. Izmest′ev

D. V. Sudarikov

S. A. Rubtsova

A. V. Kuchin

机构：

[1] Russian Academy of Sciences,Institute of Chemistry, Komi Scientific Center, Ural Branch

来源：

Chemistry of Natural Compounds | 2011年 / 47卷

关键词：

dimenthyldisulfide; dineomenthyldisulfide; menthylneomenthyldisulfide; thiosulfinate; asymmetric oxidation;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Symmetric and asymmetric disulfides were synthesized from mixtures of menthyl- and neomenthylthiols and were oxidized asymmetrically. Dineomenthyldisulfide, dimenthyldisulfide, and menthylneomenthyldisulfide were synthesized in yields of 47–48%, 24–25, and 29–55, respectively. Pure diastereomeric dimenthyl-, dineomenthyl-, and menthylneomenthylthiosulfinates were synthesized in yields of 85–90% and de up to 30%.

引用

页码：46 / 50

页数：4

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