Synthesis of several optically active menthane disulfides and thiosulfinates

被引：0
|
作者：
E. S. Izmest′ev
D. V. Sudarikov
S. A. Rubtsova
A. V. Kuchin
机构：
[1] Russian Academy of Sciences,Institute of Chemistry, Komi Scientific Center, Ural Branch
来源：
Chemistry of Natural Compounds | 2011年 / 47卷
关键词：
dimenthyldisulfide; dineomenthyldisulfide; menthylneomenthyldisulfide; thiosulfinate; asymmetric oxidation;
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摘要：
Symmetric and asymmetric disulfides were synthesized from mixtures of menthyl- and neomenthylthiols and were oxidized asymmetrically. Dineomenthyldisulfide, dimenthyldisulfide, and menthylneomenthyldisulfide were synthesized in yields of 47–48%, 24–25, and 29–55, respectively. Pure diastereomeric dimenthyl-, dineomenthyl-, and menthylneomenthylthiosulfinates were synthesized in yields of 85–90% and de up to 30%.
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页码：46 / 50
页数：4
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