An Infrared Spectroscopic Study on the Hofmann-diam-type 1,12-Diaminododecanemetal(II) Tetracyanonickelate(II)-aromatic Guest Clathrates: M(H2N(CH2)12NH2)Ni(CN)4ċG(M=Co, Ni or Cd; G = Benzene, Naphthalene, Anthracene, Phenanthrene or Biphenyl)

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作者
Mustafa Şenyel
T. Raci Sertbakan
Güneş Kürkçüoğ
Ergün Kasap
Ziya Kantarci
机构
[1] Anadolu Üniversitesi,Fen Fakültesi, Yunusemre Kampüsü
[2] Gazi Üniversitesi,Fen Edebiyat Fakültesi, Fizik Bölümü
关键词
Hofmann-type clathrates; tetracyanonickelate; 1; 12-diaminododecane; infrared spectra; benzene; naphthalene; anthracene; phenanthrene; biphenyl;
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摘要
Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminododecane) Ni(CN)4ċG (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diaminododecane molecules in the host lattice permit the inclusion of bulky guest molecules. The spectral features suggest that these compounds are similar in structure to the other Hofmann-diam-type clathrates.
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页码:175 / 180
页数:5
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