Phthalocyanines and related compounds: XLII. Synthesis of phenyl-substituted tetraazachlorins and tetraazabacteriochlorins

被引：0
|
作者：
E. A. Makarova
E. V. Dzyuina
E. A. Luk’yanets
机构：
[1] Research Institute of Organic Intermediate Products and Dyes,
来源：
Russian Journal of General Chemistry | 2006年 / 76卷
关键词：
Porphyrin; Phthalocyanine; Electronic Absorption Spectrum; Ammonium Molybdate; Nickel Complex;
D O I：
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中图分类号：
学科分类号：
摘要：
New oxidation-resistant hexaphenyl-substituted tetramethyltetraazachlorin, its nickel complex, and tetraphenyl-substituted octamethyltetraazabacteriochlorin and octamethyltetraazaisobacteriochlorin nickel complexes were synthesized for the first time by mixed condensation of diphenylm aleonitrile with tetramethylsuccinonitrile in the presence of lithium dimethylaminoethoxide or nickel chloride. The products were characterized by electronic absorption, 1H NMR, and mass spectra. Mixed condensation of diphenylsuccinonitrile with phthalonitrile in the presence of nickel chloride was found to give nickel complexes of phenylsubstituted benzo-fused tetraazaporphyrins rather than their hydrogenated derivatives.
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页码：1165 / 1169
页数：4
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