Ferrocene Derivatives of Valine and Leucine

被引：0
|
作者：
L. A. Popova
N. Ya. Yurashevich
M. S. Cherevin
T. G. Gulevich
M. D. Reshetova
V. A. Knizhnikov
机构：
[1] National Academy of Sciences of Belarus,Institute of Physical Organic Chemistry
来源：
Russian Journal of General Chemistry | 2005年 / 75卷
关键词：
Sodium; Methyl; Acetic; Ester; Ethyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Methyl and ethyl esters of valine and leucine were reacted with ferrocenecarbaldehyde to obtain azomethines (C5H5)Fe(C5H4CH=NCHRCOOR′) whose reactions with sodium borohydride provide ferrocenylmethyl derivatives (C5H5)Fe(C5H4CH2NHCHR⋅COOR′) [R=(CH3)2CH, (CH3)2CHCH2; R′ = CH3, C2H5]. The latter compounds react with sodium hydroxide to give, after treatment of the reaction mixtures with acetic acid, N-substituted amino acids (C5H5)Fe(C5H4CH2NHCHRCOOH).
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页码：990 / 992
页数：2
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