Solubility in the ternary system CaSO4 + Na2SO4 + H2O at 298.15 K

被引:0
|
作者
D. Popović
G. Stupar
J. Miladinović
M. Todorović
M. Zrilić
机构
[1] University of Belgrade,Faculty of Technology and Metallurgy
[2] Institute Kirilo Savič A. D. Belgrade,undefined
来源
Russian Journal of Physical Chemistry A | 2011年 / 85卷
关键词
solubility; ternary system CaSO; + Na; SO; + H; O; phase equilibrium;
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学科分类号
摘要
The solubility in the ternary system, aqueous mixture of CaSO4 and Na2SO4, at T = 298.15 K comprises five different salts: calcium sulfate dihydrate, mirabilite, thenardite, glauberite and labile salt. Using the Extended Pitzer’s Ion Interaction model for pure and mixed electrolyte solutions and criteria of phase equilibria, predicted solubility behavior of salts was compared with experimental results from literature. The agreement between calculated and experimental solubilities was excellent in the ionic strength range up to 10.9062 mol kg−1.
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页码:2349 / 2353
页数:4
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