[Na4(H2O)7][Fe(OH)6Mo6O18]: A new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center

被引：0
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作者：
Chuande Wu
Xiang Lin
Rongmin Yu
Wenbin Yang
Canzhong Lu
Honghui Zhuang
机构：
[1] Fujian Institute of Research on the Structure of Matter,State Key Laboratory of Structural Chemistry
[2] Chinese Academy of Sciences,undefined
来源：
Science in China Series B: Chemistry | 2001年 / 44卷
关键词：
[12] metallacrown-6 structure; ring-shaped cluster; three-dimensional network; ESR;
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摘要：
The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (∼0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions.
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页码：49 / 54
页数：5
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