Molecular-mass distribution during radical polymerization of acrylates initiated by pulse laser radiation

被引：0
|
作者：
A. N. Nikitin
机构：
[1] Russian Academy of Sciences,Institute on Laser and Information Technologies
来源：
Polymer Science Series B | 2009年 / 51卷
关键词：
Laser Radiation; Acrylate; Polymer Science Series; Radical Polymerization; Chain Transfer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The analytical expressions for the calculation of the molecular-mass distributions for the polymerization of acrylates initiated by the pulse periodic radiation are derived. The intramolecular chain transfer to the polymer is shown to be responsible for the known abnormalities in the molecular-mass distributions during the polymerization of acrylates. A relationship is derived for the characterization of the periodic structure of the molecular-mass distributions and for confirmation of the applicability of the first peak for estimating the avarage rate constant of chain growth.
引用
收藏
页码：195 / 203
页数：8
相关论文
共 50 条
  • [21] MOLECULAR-MASS DISTRIBUTION OF CHITIN AND CHITOSAN
    HASEGAWA, M
    ISOGAI, A
    ONABE, F
    CARBOHYDRATE RESEARCH, 1994, 262 (01) : 161 - 166
  • [22] Living radical polymerization of acrylates initiated and controlled by organocobalt porphyrin complexes
    Univ of Pennsylvania, Philadelphia, United States
    Macromolecules, 26 (8109-8112):
  • [23] Living radical polymerization of acrylates initiated and controlled by organocobalt porphyrin complexes
    Wayland, BB
    Basickes, L
    Mukerjee, S
    Wei, ML
    Fryd, M
    MACROMOLECULES, 1997, 30 (26) : 8109 - 8112
  • [24] Living radical polymerization of acrylates initiated and controlled by organocobalt(III) complexes
    Wayland, B.B.
    Fryd, M.
    Mukerjee, S.
    Poszmik, G.
    Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, 73
  • [25] LIVING RADICAL POLYMERIZATION OF ACRYLATES INITIATED AND CONTROLLED BY ORGANOCOBALT(III) COMPLEXES
    WAYLAND, BB
    FRYD, M
    MUKERJEE, S
    POSZMIK, G
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 230 - PMSE
  • [26] MOLECULAR-MASS DISTRIBUTION IN HOMOPOLYMERIC INDUSTRY
    ENIKOLOPYAN, NS
    GLEIZER, RG
    USPEKHI KHIMII, 1979, 48 (10) : 1833 - 1855
  • [27] MOLECULAR-MASS DISTRIBUTION OF CARD POLYNAPHTHOYLENEIMIDE
    VYGODSKY, YS
    MOLODTSOVA, ED
    VINOGRADOVA, SV
    TIMOFEEVA, GI
    PAVLOVA, SSA
    KORSHAK, VV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA B, 1979, 21 (02): : 100 - 104
  • [28] Asphaltene Molecular-Mass Distribution Determined by Two-Step Laser Mass Spectrometry
    Pomerantz, Andrew E.
    Hammond, Matthew R.
    Morrow, Amy L.
    Mullins, Oliver C.
    Zare, Richard N.
    ENERGY & FUELS, 2009, 23 (3-4) : 1162 - 1168
  • [29] MOLECULAR-MASS DISTRIBUTION OF POLYMERS AS A METHOD OF INVESTIGATION OF COMPLEX POLYMERIZATION PROCESSES - CATIONIC POLYMERIZATION OF CYCLIC ETHERS
    TAGANOV, NG
    KOROVINA, GV
    ENTELIS, SG
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1978, 20 (06): : 1393 - 1399
  • [30] SOLUTION OF THE REVERSE KINETIC POLYMERIZATION PROBLEM USING DATA ON THE MOLECULAR-MASS POLYMER DISTRIBUTION
    PODOSENOVA, NG
    BUDTOV, VP
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1988, 31 (02): : 3 - 16
12345