Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er)

被引：0
|
作者：
V. S. Kurazhkovskaya
E. A. Dobretsova
E. Yu. Borovikova
V. V. Mal’tsev
N. I. Leonyuk
机构：
[1] M. V. Lomonosov Moscow State University,
来源：
Journal of Structural Chemistry | 2011年 / 52卷
关键词：
IR spectroscopy; factor group analysis; rare-earth chromium borates;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Rare-earth chromium borates RCr3(BO3)4, where R = La-Er, obtained as a result of spontaneous solutionmelt crystallization and belonging to two polytypic modifications (R32 (D37) and C2/c (C2h6) space groups) are studied by infrared spectroscopy with the factor group analysis of vibrations. Borates with R = La-Nd are shown to crystallize in the monoclinic C2/c space group. Borates with R = Sm-Er in the 1:1 ratio of batch and solvent form rhombohedral (R32 space group) and monoclinic (C2/c space group) phases at the 2.3:1 ratio, except EuCr3(BO3)4 and GdCr3(BO3)4 that have the rhombohedral structure under all crystallization conditions. Both rhombohedral and monoclinic polytypes may contain oppositely ordered layers. Y-, Tm-, Yb-, Lu-chromium borates are not formed.
引用
收藏
页码：699 / 707
页数：8
相关论文
共 50 条
  • [41] Elastic, piezoelectric, and dielectric properties of rare-earth calcium oxoborates RCa4O(BO3)3 (R = Er, Y, Dy, Gd, Sm, Nd, La)
    Muenchhalfen, Marie
    Schreuer, Juergen
    Reuther, Christoph
    Mehner, Erik
    Stoecker, Hartmut
    JOURNAL OF APPLIED PHYSICS, 2021, 130 (09)
  • [42] LUMINESCENCE OF RARE-EARTH IONS IN CA3(BO3)2
    VANDERVOORT, D
    DERIJK, JME
    VANDOORN, R
    BLASSE, G
    MATERIALS CHEMISTRY AND PHYSICS, 1992, 31 (04) : 333 - 339
  • [43] STRUCTURAL INVESTIGATIONS OF NEW CALCIUM RARE-EARTH (R) OXYBORATES WITH THE COMPOSITION CA4RO(BO3)3
    NORRESTAM, R
    NYGREN, M
    BOVIN, JO
    CHEMISTRY OF MATERIALS, 1992, 4 (03) : 737 - 743
  • [44] Investigation of the iron borates DyFe3(BO3)4 and HoFe3(BO3)4 by the method of Er3+ spectroscopic probe
    Stanislavchuk, T. N.
    Chukalina, E. P.
    Popova, M. N.
    Bezmatemykh, L. N.
    Gudim, I. A.
    PHYSICS LETTERS A, 2007, 368 (05) : 408 - 411
  • [45] EPR of Nd3+ and Er3+ ions in aluminum borates YAl3(BO3)4 and EuAl3(BO3)4
    Prokhorov, A. D.
    Prokhorov, A. A.
    Chernysh, L. F.
    Aleshkevich, P.
    Dyakonov, V.
    Szymczak, H.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2013, 326 : 162 - 165
  • [46] Effect of a Rare-Earth Ion on the Structural Instability in RFe3(BO3)4 Crystals
    Pavlovskiy, M. S.
    Zinenko, V. I.
    Shinkorenko, A. S.
    JETP LETTERS, 2018, 108 (02) : 116 - 120
  • [47] Effect of a Rare-Earth Ion on the Structural Instability in RFe3(BO3)4 Crystals
    M. S. Pavlovskiy
    V. I. Zinenko
    A. S. Shinkorenko
    JETP Letters, 2018, 108 : 116 - 120
  • [48] RARE-EARTH ALUMINUM BORATE OF THE SEAL3(BO3)4 TYPE WITH MONOCLINIC SYMMETRY
    BARTSCH, HH
    JARCHOW, O
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1982, 159 (1-4): : 13 - 14
  • [49] Redistribution of rare-earth dopants (Eu, Dy, Ho, Er, Tm, Yb) in LaSc3(BO3)4 structure and influence on optical properties
    Kokh, K. A.
    Jamous, A. Y.
    Svetlichny, V. A.
    Kuznetsov, A. B.
    Yelisseyev, A. P.
    Bogdanov, N. E.
    Goreyavcheva, A. A.
    Kokh, A. E.
    OPTICAL MATERIALS, 2025, 159
  • [50] Potassium rich rare earth (RE) borates K3RE(BO3)2
    Gao, J. H.
    Li, R. K.
    SOLID STATE SCIENCES, 2008, 10 (01) : 26 - 30
12345