The active site of low-temperature methane hydroxylation in iron-containing zeolites

被引:0
|
作者
Benjamin E. R. Snyder
Pieter Vanelderen
Max L. Bols
Simon D. Hallaert
Lars H. Böttger
Liviu Ungur
Kristine Pierloot
Robert A. Schoonheydt
Bert F. Sels
Edward I. Solomon
机构
[1] Stanford University,Department of Chemistry
[2] Centre for Surface Chemistry and Catalysis,Department of Microbial and Molecular Systems
[3] KU Leuven – University of Leuven,Department of Chemistry
[4] Celestijnenlaan 200F,undefined
[5] KU Leuven,undefined
[6] Celestijnenlaan 200F,undefined
[7] Photon Science,undefined
[8] SLAC National Accelerator Laboratory,undefined
[9] † Present address: Division of Theoretical Chemistry,undefined
[10] Lund University,undefined
[11] PO Box 124,undefined
[12] 221 00 Lund,undefined
[13] Sweden.,undefined
来源
Nature | 2016年 / 536卷
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摘要
Iron-containing zeolites have an exceptional ability to convert methane into methanol, but their active site have been hard to study; now, magnetic circular dichroism has been used to explore the reactive species, providing a technique that should be generally applicable, and revealing the value of constraining active sites within a lattice to improve catalyst functionality.
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页码:317 / 321
页数:4
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