Generation of Electrophilic Iodine from Iodine Monochloride in Neutral Media. Iodination and Protodeiodination of Carbazole

被引：0
|
作者：
V. D. Filimonov
E. A. Krasnokutskaya
Yu. A. Lesina
机构：
[1] Tomsk Polytechnic University,
来源：
Russian Journal of Organic Chemistry | 2003年 / 39卷
关键词：
Oxidation; Oxygen; Chloride; Acetic Acid; Acetonitrile;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In reaction of iodine monochloride with CF3COOAg, CH3COONa or (CH3COO)2Pb in acetonitrile and acetic acid the chloride is bonded by metal cations, and electrophilic iodine is generated able to easily iodinate anthracene and carbazole. However at the iodination of anthracene in the presence of oxygen the prevailing process is anthracene oxidation to anthraquinone. In the presence of sulfuric acid protodeiodination of 3-iodocarbazole was found to occur resulting in rearranged products.
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页码：875 / 880
页数：5
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