Thermodynamic interaction and mechanical characteristics of Nylon 6 and polyhedral oligomeric silsesquioxane nanohybrids

被引：0

作者：

Sang-Kyun Lim

Eun-Pyo Hong

Yu-Hyun Song

Hyoung Jin Choi

In-Joo Chin

机构：

[1] Inha University,Department of Polymer Science and Engineering

[2] IBM Almaden Research Center,undefined

来源：

Journal of Materials Science | 2012年 / 47卷

关键词：

Poss; Solubility Parameter; Semicrystalline Polymer; Melting Point Depression; Equilibrium Melting Temperature;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Polyhedral oligomeric silsesquioxane (POSS) reagents have unique hybrid chemical compositions containing nano-sized cage structures with dimensions comparable to those of most polymer segments and coils. This article reports a generalized functionalization scheme of POSS that is suitable as a nanohybrid with Nylon 6. The thermodynamic interaction energy density, thermodynamic solubility parameter, and activation energy of the specific interaction between Nylon 6 and POSS were examined. The mechanical, thermal, and morphological properties of the Nylon 6 nanohybrids were also analyzed and compared with the theoretical estimation.

引用

页码：308 / 314

页数：6

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