Acid–Basic Properties of Al(III), Ga(III), and In(III) Complexes with Octaphenyltetraazaporphine

被引：0
|
作者：
S. S. Ivanova
P. A. Stuzhin
机构：
[1] Ivanovo State Academy of Chemical Technology,
来源：
Russian Journal of Coordination Chemistry | 2004年 / 30卷
关键词：
Physical Chemistry; Nitrite; Acidic Form; Basic Property; Halide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Al(III), Ga(III), and In(III) complexes with octaphenyltetraazaporphine and halide axial ligands of the composition [(X)MTAP] (X = F, Cl, Br) and In(III) complexes with bidentate ligands of the composition [(Y)InTAP] (Y = nitrite (NO2) and 2,3-naphthodiolate (NpO2)) were synthesized. The acid–basic properties of the complexes were studied in the proton-donor media and the concentration stability constants of the acidic forms obtained at the first protonation stage were determined. The effect of the nature of a metal and extra ligand on the basic properties of meso-nitrogen atom in macrocyclic ligand was discussed.
引用
收藏
页码：765 / 773
页数：8
相关论文
共 50 条
  • [21] Detection of Al(III) and Ga(III) complexes with morin by electrospray ionization mass spectrometry
    Septhum, Chutima
    Morgan, Jody
    Hick, Larry
    Bremner, John B.
    Rattanaphani, Saowanee
    Rattanaphani, Vichitr
    ANALYTICAL SCIENCES, 2007, 23 (10) : 1209 - 1214
  • [22] METAL-ION CATALYZED ACID-HYDROLYSIS OF ACIDOPENTAAMMINE COBALT(III) COMPLEXES - KINETICS AND MECHANISM OF AL(III), GA(III) AND IN(III) CATALYZED-HYDROLYSIS OF MALONATOPENTAAMMINECOBALT(III) COMPLEX
    DASH, AC
    NANDA, RK
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (10): : 2139 - 2144
  • [23] STUDY OF THE COMPLEXES FORMED BY FURFURYLIMINO DIACETIC ACID WITH CO(III), BI(III), AU(III) AND AL(III) CATIONS
    CAPLTAN, F
    ALONSO, EJ
    VALENCIA, MC
    AFINIDAD, 1981, 38 (376) : 544 - 547
  • [24] APPLICATION OF CU (II) THIOMALLIC ACID COMPLEX AS AN INDICATOR IN COMPLEXOMETRIC DETERMINATION OF AL(III), GA(III) AND IN(III)
    SANE, RT
    KARANDIKAR, RK
    KULKARNI, AG
    CURRENT SCIENCE, 1976, 45 (20): : 721 - 721
  • [25] COMPLEXES OF SOME METALS WITH QUERCETIN-5'-SULFONIC ACID (QSA) .1. COMPLEX-COMPOUNDS OF AL(III),GA(III) AND IN(III)
    KOPACZ, M
    BARTECKI, A
    ROCZNIKI CHEMII, 1974, 48 (12): : 2259 - 2266
  • [26] COMPLEXES OF AL(III), GA(III), AND IN(III) IONS WITH SODIUM-SALT OF MORIN-5'-SULFONIC ACID (NAMSA) IN AQUEOUS-SOLUTIONS
    KOPACZ, M
    POLISH JOURNAL OF CHEMISTRY, 1989, 63 (1-3) : 19 - 25
  • [27] COMPLEXES OF 5-PHENYLAZO-8-QUINOLINOL WITH AL(III), GA(III), IN(III) AND T1(I)
    KHATER, MM
    ISSA, YM
    SHOUKRY, AF
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1979, 17 (05): : 472 - 475
  • [28] Cytotoxicity studies, DNA interaction and protein binding of new Al (III), Ga (III) and In (III) complexes with 5-hydroxyflavone
    Munteanu, Alexandra-Cristina
    Badea, Mihaela
    Olar, Rodica
    Silvestro, Luigi
    Mihaila, Mirela
    Brasoveanu, Lorelei Irina
    Musat, Mihaela Georgiana
    Andries, Adrian
    Uivarosi, Valentina
    APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (12)
  • [29] Ga(III) pyridinecarboxylate complexes: potential analogues of the second generation of therapeutic Ga(III) complexes?
    Rendosova, Michaela
    Gyepes, Robert
    Sovova, Simona
    Sabolova, Danica
    Vilkova, Maria
    Olejnikova, Petra
    Kello, Martin
    Lakatos, Boris
    Vargova, Zuzana
    JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2023, 28 (06): : 591 - 611
  • [30] Ga(III) pyridinecarboxylate complexes: potential analogues of the second generation of therapeutic Ga(III) complexes?
    Michaela Rendošová
    Róbert Gyepes
    Simona Sovová
    Danica Sabolová
    Mária Vilková
    Petra Olejníková
    Martin Kello
    Boris Lakatoš
    Zuzana Vargová
    JBIC Journal of Biological Inorganic Chemistry, 2023, 28 : 591 - 611
12345