Acid–Basic Properties of Al(III), Ga(III), and In(III) Complexes with Octaphenyltetraazaporphine

被引：0
|
作者：
S. S. Ivanova
P. A. Stuzhin
机构：
[1] Ivanovo State Academy of Chemical Technology,
来源：
Russian Journal of Coordination Chemistry | 2004年 / 30卷
关键词：
Physical Chemistry; Nitrite; Acidic Form; Basic Property; Halide;
D O I：
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学科分类号：
摘要：
Al(III), Ga(III), and In(III) complexes with octaphenyltetraazaporphine and halide axial ligands of the composition [(X)MTAP] (X = F, Cl, Br) and In(III) complexes with bidentate ligands of the composition [(Y)InTAP] (Y = nitrite (NO2) and 2,3-naphthodiolate (NpO2)) were synthesized. The acid–basic properties of the complexes were studied in the proton-donor media and the concentration stability constants of the acidic forms obtained at the first protonation stage were determined. The effect of the nature of a metal and extra ligand on the basic properties of meso-nitrogen atom in macrocyclic ligand was discussed.
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页码：765 / 773
页数：8
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