Solvation dynamics of a charge bubble in water

被引：0
|
作者：
Ranjit Biswas
Biman Bagchi
机构：
[1] Indian Institute of Science,Solid State and Structural Chemistry Unit
[2] Jawaharlal Nehru Centre for Advanced Scientific Research,undefined
来源：
Proceedings / Indian Academy of Sciences | 1997年 / 109卷 / 5期
关键词：
Solvation dynamics; ultrafast spectroscopy; ionic mobility; electron solvation;
D O I：
10.1007/BF02875977
中图分类号：
学科分类号：
摘要：
A microscopic theory is used to calculate the solvation-time correlation function, (S(t)), of a light, non-stationary charge bubble in water. The calculated correlation function is found to be similar to the energy-time correlation function of a solvated electron. The ionic mobility of a charge bubble of the size of the hydrated electron is also calculated. It is found that the mobility of the charge plays a very important role in its own solvation.
引用
收藏
页码：347 / 352
页数：5
相关论文
共 50 条
  • [41] DYNAMICS OF BUBBLE-GROWTH IN WATER ELECTROLYSIS
    NEFEDOV, VG
    MATVEEV, VV
    SEREBRITSKII, VM
    KSENZHEK, OS
    CHIKOLBA, TY
    SOVIET ELECTROCHEMISTRY, 1991, 27 (04): : 443 - 448
  • [42] Polar solvation dynamics in water and methanol: search for molecularity
    Sajadi, Mohsen
    Weinberger, Michael
    Wagenknecht, Hans-Achim
    Ernsting, Nikolaus P.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (39) : 17768 - 17774
  • [43] Solvation of asphaltenes in supercritical water: A molecular dynamics study
    Xin, Shuang-Mei
    Liu, Qing-Kun
    Wang, Kai
    Chen, Yi
    Yuan, Pei-Qing
    Cheng, Zhen-Min
    Yuan, Wei-Kang
    CHEMICAL ENGINEERING SCIENCE, 2016, 146 : 115 - 125
  • [44] Intramolecular charge transfer and solvation dynamics of Nile Red in the nanocavity of cyclodextrins
    Hazra, P
    Chakrabarty, D
    Chakraborty, A
    Sarkar, N
    CHEMICAL PHYSICS LETTERS, 2004, 388 (1-3) : 150 - 157
  • [45] Solvation Dynamics of Wet Ethaline: Water is the Magic Component
    Alfurayj, Ibrahim
    Fraenza, Carla Cecilia
    Zhang, Yong
    Pandian, Rathiesh
    Spittle, Stephanie
    Hansen, Bryce
    Dean, William
    Gurkan, Burcu
    Savinell, Robert
    Greenbaum, Steve
    Maginn, Edward
    Sangoro, Joshua
    Burda, Clemens
    JOURNAL OF PHYSICAL CHEMISTRY B, 2021, 125 (31): : 8888 - 8901
  • [46] Slow solvation dynamics of a water-nitrobenzene system
    Moakes, Greg
    Janata, Jiri
    ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (08) : 720 - 728
  • [47] Solvation dynamics at water-ZrO2 interfaces
    Tortschanoff, A
    Portuondo, E
    van Mourik, F
    Moser, JE
    Steinemann, S
    Chergui, M
    FEMTOCHEMISTRY AND FEMTOBIOLOGY: ULTRAFAST EVENTS IN MOLECULAR SCIENCE, 2004, : 541 - 544
  • [48] Inertial water response dominates protein solvation dynamics
    Bizimana, Laurie A.
    Epstein, Jordan
    Turner, Daniel B.
    CHEMICAL PHYSICS LETTERS, 2019, 728 : 1 - 5
  • [49] SOLVATION - MOLECULAR-DYNAMICS STUDY OF A DIPEPTIDE IN WATER
    ROSSKY, PJ
    KARPLUS, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (08) : 1913 - 1937
  • [50] Electron solvation in water clusters following charge transfer from iodide
    Verlet, JRR
    Kammrath, A
    Griffin, GB
    Neumark, DM
    JOURNAL OF CHEMICAL PHYSICS, 2005, 123 (23):
12345