Enzymatic synthesis of bioactive compounds by Rhus laccase from Chinese Rhus vernicifera

被引：1
|
作者：
YunYang Wan
Rong Lu
Kazuhiro Akiyama
Tetsuo Miyakoshi
YuMin Du
机构：
[1] Chinese University of Petroleum,Key Laboratory for Hydrocarbon Accumulation Mechanism, Ministry of Education, Faculty of Natural Resources and Information Technology
[2] Meiji University,Department of Industrial Chemistry, School of Science and Technology
[3] Wuhan University,School of Resource and Environment Science
来源：
Science in China Series B: Chemistry | 2007年 / 50卷
关键词：
lignan; laccases; pinoresinol; dehydrogenative polymers; enzymatic mechanism;
D O I：
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中图分类号：
学科分类号：
摘要：
A simple one step synthesis of pinoresinol and its derivatives-active components of Du-Zhong (Eucommia ulmoides)-from coniferyl alcohol and p-courmaryl alcohol with higher yields was achieved by Rhus laccases (RL) catalysis in water miscible organic solvents. Biomacromolecules dehydrogenative polymers (DHP) were only synthesized by fungal laccases, not by RL. The structures and the reaction mechanism were discussed to promote the understanding of the function of laccases in the process of lignin biosynthesis.
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页码：179 / 182
页数：3
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