Ionization energy of core electrons in haloderivatives. Polarization effect in F-, Cl-, Br-, and I-centered radical cations

被引：0

作者：

N. M. Khamaletdinova

A. N. Egorochkin

O. V. Kuznetsova

机构：

[1] Russian Academy of Sciences,Razuvaev Institute of Organometallic Chemistry

来源：

Russian Journal of General Chemistry | 2009年 / 79卷

关键词：

General Chemistry; Bond Energy; Valence Electron; Polarization Effect; Reaction Series;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Ionization energies of core electrons of the fluorine, chlorine, bromine, and iodine atoms in 27 reaction series of haloderivatives depend on the inductive, the resonance, and the polarization effect; the latter has not been considered before. The contribution of the polarization effect varies in a broad range and in some cases exceeds 50%. Halocentered radical cations formed by the abstraction of the core or valence electron from the molecule slightly differ in the polarization effect value.

引用

页码：2175 / 2182

页数：7

共 42 条

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