Iron(II) clathrochelate with an annelated 4,5-dimercapto-[1,3]dithiol-2-thione moiety: Synthesis, structure, and redox reactions

被引：0
|
作者：
M. A. Vershinin
A. B. Burdukov
N. V. Pervukhina
I. V. Eltsov
E. G. Boguslavskii
Ya. Z. Voloshin
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,Nesmeyanov Institute of Organoelement Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2015年 / 60卷
关键词：
Electron Paramagnetic Resonance; Heterocyclic Moiety; Redox Conversion; Cage Complex; Dimercapto;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Nucleophilic substitution of chlorine atoms in iron(II) dichloroclathrochelate induced by 4,5-dimercapto-[1,3]dithiol-2-thione dianion gave rise to a cage complex with an annelated sulfur-containing heterocyclic moiety. The composition and structure of this complex were determined by X-ray crystallography and multinuclear NMR spectroscopy in a crystal and in solution, respectively; cyclic voltammetry (CVA) and EPR were used to study the redox reactions of the complex in solution to yield a ligand-centered radical-anionic product.
引用
收藏
页码：861 / 865
页数：4
相关论文
共 50 条
  • [31] UNUSUAL STRUCTURE-RELATED MAGNETISM IN THE ORGANIC CONDUCTOR TSF(NI(DMIT)2)3 (TETRASELENAFULVALENIUM-TRI-(BIS-(4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONE)NICKEL)-ATE)
    JOHANNSEN, I
    BECHGAARD, K
    RINDORF, G
    THORUP, N
    JACOBSEN, CS
    MORTENSEN, K
    SYNTHETIC METALS, 1986, 15 (04) : 333 - 343
  • [32] ALKYLATION REACTIONS OF 4,5-BIS(TRIFLUOROMETHYL)-1,3-DITHIOLE-2-THIONE - A 1ST X-RAY STRUCTURE DETERMINATION OF A 2-ALKYLTHIO-1,3-DITHIOLIUM SALT
    FRASCH, M
    MONO, S
    PRITZKOW, H
    SUNDERMEYER, W
    CHEMISCHE BERICHTE-RECUEIL, 1993, 126 (01): : 273 - 275
  • [33] The 3-[3α(2α-hydroxy)pinane]-4,5-(pinan)-1,3-oxazolidine synthesis, structure and properties
    Bialek, Magdalena
    Trzesowska, Agata
    Kruszynski, Rafal
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2007, 28 (01) : 89 - 94
  • [34] 5,7-Dichloro-1,3-dithiolo-[4,5-d]pyrimidine-2-thione and -2-selone: Synthesis, crystal structure, solvatochromism, and reactions with nucleophiles
    Neilands O.
    Valters R.
    Belyakov S.V.
    Chemistry of Heterocyclic Compounds, 2002, 38 (1) : 79 - 85
  • [35] Crystal structure of [3-(4,5-dihydro-1,3-thiazolin-2yl-kappa N)-1,3-thiazolidine-2-thione-kappa S-2](1,3-thiazolidine-2-thione-kappa S-2)copper(I) nitrate
    Saithong, Saowanit
    Klongkleaw, Pirawan
    Pakawatchai, Chaveng
    Mokakul, Jedsada
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2014, 70 : 91 - +
  • [36] Crystal structure and band parameters of mixed crystals derived from quantum spin liquid β′-EtMe3Sb[Pd(dmit)2]2 (dmit=1,3-dithiol-2-thione-4,5-dithiolate)
    Kato, Reizo
    Fukunaga, Takeo
    Yamamoto, Hiroshi M.
    Ueda, Kohei
    Hengbo, Cui
    PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2012, 249 (05): : 999 - 1003
  • [37] Studies on pyrimidine-annelated heterocycles: Synthesis of novel pyrazolo[3',4':4,5]pyrido[2,3-d]pyrimidines by intramolecular 1,3-dipolar cycloadditions
    Baruah, B
    Prajapati, D
    Sandhu, JS
    Ghosh, AC
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1996, (16): : 1999 - 2003
  • [38] IN(III), TL(III) AND V(IV) TRIS-CHELATES OF THE HETEROCYCLIC DITHIOLENE AND DISELENOLENE LIGANDS 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE (DMIT), 1,2-DITHIOLE-3-THIONE-4,5-DITHIOLATE (DMT) AND 1,3-DISELENOLE-2-SELONE-4,5-DISELENOLATE (DSIS) - CRYSTAL AND MOLECULAR-STRUCTURE OF (BU4N)2[V(DMT)3]4
    OLK, RM
    DIETZSCH, W
    KIRMSE, R
    STACH, J
    HOYER, E
    GOLIC, L
    INORGANICA CHIMICA ACTA, 1987, 128 (02) : 251 - 259
  • [39] Studies on pyrimidine-annelated heterocycles: synthesis of novel pyrazolo [3',4':4,5] pyrido-[2,3-d]pyrimidines by intramolecular 1,3-dipolar cycloadditions
    J Chem Soc Perkin Trans 1, 16 (1999):
  • [40] Synthesis, structure, and photoluminescence properties of bis[2-(1,3-benzoxazol-2-yl-κN)-4,5-dichloro-3-(ethoxycarbonyl)phenolato-κO]zinc(II)
    Sayapin, Yu. A.
    Nikolaevskii, S. A.
    Makarova, N. I.
    Gusakov, E. A.
    Tupaeva, I. O.
    Dorogan, I. V.
    Metelitsa, A. V.
    Minkin, V. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2016, 52 (07) : 1018 - 1021
12345