Iron(II) clathrochelate with an annelated 4,5-dimercapto-[1,3]dithiol-2-thione moiety: Synthesis, structure, and redox reactions

被引：0
|
作者：
M. A. Vershinin
A. B. Burdukov
N. V. Pervukhina
I. V. Eltsov
E. G. Boguslavskii
Ya. Z. Voloshin
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,Nesmeyanov Institute of Organoelement Compounds
[3] Russian Academy of Sciences,undefined
来源：
Russian Journal of Inorganic Chemistry | 2015年 / 60卷
关键词：
Electron Paramagnetic Resonance; Heterocyclic Moiety; Redox Conversion; Cage Complex; Dimercapto;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Nucleophilic substitution of chlorine atoms in iron(II) dichloroclathrochelate induced by 4,5-dimercapto-[1,3]dithiol-2-thione dianion gave rise to a cage complex with an annelated sulfur-containing heterocyclic moiety. The composition and structure of this complex were determined by X-ray crystallography and multinuclear NMR spectroscopy in a crystal and in solution, respectively; cyclic voltammetry (CVA) and EPR were used to study the redox reactions of the complex in solution to yield a ligand-centered radical-anionic product.
引用
收藏
页码：861 / 865
页数：4
相关论文
共 50 条
  • [1] Iron(II) Clathrochelate with an Annelated 4,5-Dimercapto-[1,3]Dithiol-2-Thione Moiety: Synthesis, Structure, and Redox Reactions
    Vershinin, M. A.
    Burdukov, A. B.
    Pervukhina, N. V.
    Eltsov, I. V.
    Boguslavskii, E. G.
    Voloshin, Ya. Z.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2015, 60 (07) : 861 - 865
  • [2] NEW EASY METHOD OF THE 1,3-DITHIOOLANE-2-THIONE SYNTHESIS AND THEIR APPLICATION FOR THE SYNTHESIS OF 4,5-DIMETHOXYCARBONYL-1,3-DITHIOL-2-THIONE
    KHODORKOVSKII, VY
    POIKAN, YY
    KREITSBERGA, YN
    NEILAND, OY
    ZHURNAL ORGANICHESKOI KHIMII, 1985, 21 (06): : 1345 - 1348
  • [3] SYNTHESIS, STRUCTURE AND PROPERTIES OF BIS(1,3-DITHIOL-2-THIONE-4,5-DITHIOLATO)AURATE OF TRIMETHYLSULFONIUM
    NAGAPETYAN, SS
    ARAKELOVA, ER
    BELOUSOVA, LV
    STRUCHKOV, YT
    UKHIN, LY
    SHKLOVER, VE
    ZHURNAL NEORGANICHESKOI KHIMII, 1988, 33 (01): : 160 - 165
  • [4] SYNTHESIS AND STRUCTURE OF TETRABUTYLAMMONIUM BIS-(1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE)AURIATE
    MACHARASHVILI, AA
    BELOUSOVA, LV
    MORKOVNIK, ZS
    STRUCHKOV, YT
    UKHIN, LY
    SHKLOVER, VE
    ZHURNAL NEORGANICHESKOI KHIMII, 1987, 32 (08): : 1897 - 1900
  • [5] 3-[4,5-bis(2-cyanoethylsulfanyl)-1,3-dithiol-2-yl]-1,3-thiazolidine-2-thione
    Yang, Wei
    Ren, Zhi-Gang
    Dai, Jie
    Ng, Seik Weng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2598 - U1112
  • [6] Synthesis and photoreactivity of 4,5-dithienyl[1,3]dithiol-2-ones
    Celli, AM
    Donati, D
    Ponticelli, F
    JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (18): : 7115 - 7118
  • [7] SYNTHESIS AND CHARACTERIZATION OF [M(DMIT)2]2- AND [M(DMT)2]2- COMPLEXES (M = SEII OR TEII - DMIT = 4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONE AND DMT = 4,5-DIMERCAPTO-1,2-DITHIOLE-3-THIONE)
    SINGH, JD
    SINGH, HB
    POLYHEDRON, 1993, 12 (23) : 2849 - 2856
  • [8] Syntheses, crystal structures and DFT calculations of 2-[4,5-bis(ethylsulfanyl)-1,3-dithiol-2-ylidene]-5-(4,5-diiodo-1, 3-dithiol-2-ylidene)-1,3-dithiolan-4-thione and -one
    Ueda, K.
    Suzuki, K.
    Suzuki, K.
    Yoza, K.
    Ishida, T.
    PHYSICA B-CONDENSED MATTER, 2010, 405 (11) : S69 - S74
  • [9] Synthesis and Crystal Structure of the Copper(I) Chloride Complex with 4,5(4-Pyridylethylene)dithio-1,3-dithiol-2-thione and Triphenylphosphine
    A. Yu. Koshevaya
    V. A. Starodub
    Russian Journal of Coordination Chemistry, 2005, 31 : 436 - 439
  • [10] EFFECT OF PRESSURE ON THE SUPERCONDUCTING TRANSITION-TEMPERATURE OF TETRATHIOFULVALENE BIS-[BIS-(4,5-DIMERCAPTO-1,3-DITHIOL-2-THIONE) NICKEL(II)] (TTF[NI(DMIT)2]2)
    SCHIRBER, JE
    OVERMYER, DL
    WILLIAMS, JM
    WANG, HH
    VALADE, L
    CASSOUX, P
    PHYSICS LETTERS A, 1987, 120 (02) : 87 - 88
12345