Calculation of the molecular-mass distribution for hyperbranched macromolecules synthesized by living three-dimensional radical polymerization

被引：0
|
作者：
S. A. Kurochkin
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Polymer Science Series B | 2010年 / 52卷
关键词：
Polymer Science Series; Hyperbranched Polymer; Molecular Mass Distribution; Monovinyl; Critical Conversion;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Kinetic analysis of the scheme underlying the formation of branched and hyperbranched macro- molecules formed by living three-dimensional radical po lymerization in the pregel period makes it possible to derive some theoretical dependences relating the conditions of polymerization and the molecular-mass distribution of polymers. In this case, a polymer product constitutes a mixture of macromolecules with different degrees of branching, and the fractional weight of macromolecules with hyperbranched structure is no more than one-third with respect to the overall polymer product.
引用
收藏
页码：109 / 117
页数：8
相关论文
共 50 条
  • [31] Critical conversion during three-dimensional living polymerization
    Korolev, GV
    Irzhak, TF
    Irzhak, VI
    POLYMER SCIENCE SERIES A, 2001, 43 (06) : 594 - 598
  • [32] Critical conversion during three-dimensional living polymerization
    Korolev, G.V.
    Irzhak, T.G.
    Irzhak, V.I.
    2001, MAIK Nauka (43):
  • [33] MOLECULAR-MASS DISTRIBUTION OF POLYSTYRENE SYNTHESIZED IN PRESENCE OF TRIFLUOROACETIC-ACID AND MANGANESE TRIACETYLACETONATE
    BELOGORODSKAYA, KV
    TARKOVA, EP
    PODOSENOVA, NG
    BUDTOV, VP
    NIKOLAEV, AF
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1977, 19 (06): : 1302 - 1306
  • [34] MOLECULAR-MASS DISTRIBUTION OF POLYMERS AS A METHOD OF INVESTIGATION OF COMPLEX POLYMERIZATION PROCESSES - CATIONIC POLYMERIZATION OF CYCLIC ETHERS
    TAGANOV, NG
    KOROVINA, GV
    ENTELIS, SG
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1978, 20 (06): : 1393 - 1399
  • [35] SOLUTION OF THE REVERSE KINETIC POLYMERIZATION PROBLEM USING DATA ON THE MOLECULAR-MASS POLYMER DISTRIBUTION
    PODOSENOVA, NG
    BUDTOV, VP
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1988, 31 (02): : 3 - 16
  • [36] Comparison of the properties of dimethacrylate-styrene copolymers prepared by conventional and living three-dimensional radical polymerization
    Korolev, GV
    Kochneva, IS
    Bakova, GM
    Berezin, MP
    Makhonina, LI
    POLYMER SCIENCE SERIES A, 2002, 44 (09) : 936 - 940
  • [37] Dendrimers and hyperbranched polymers: Two families of three-dimensional macromolecules with similar but clearly distinct properties
    Frechet, JMJ
    Hawker, CJ
    Gitsov, I
    Leon, JW
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1996, A33 (10): : 1399 - 1425
  • [38] TERMINI: A universal method for the synthesis of hyperbranched and dendritic macromolecules from conventional monomers via living radical polymerization.
    Percec, V
    Barboiu, B
    Bera, TK
    Grigoras, C
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U437 - U438
  • [39] The three-dimensional mass distribution in NGC 1700
    Statler, TS
    Dejonghe, H
    Smecker-Hane, T
    ASTRONOMICAL JOURNAL, 1999, 117 (01): : 126 - 139
  • [40] Three-dimensional calculation of current distribution in electrodeposition of copper
    Jeon, SH
    Choi, YS
    Kim, NS
    Kang, T
    Sohn, HJ
    AQUEOUS ELECTROTECHNOLOGIES, 1997, : 63 - 71
12345