Thermodynamics of L-valine complex formation with Cu2+ ions in an aqueous solution

被引：0
|
作者：
G. G. Gorboletova
S. N. Gridchin
A. A. Lutsenko
机构：
[1] Ivanovo State University of Chemical Technology,
来源：
Russian Journal of Coordination Chemistry | 2010年 / 36卷
关键词：
Ionic Strength; Coordination Chemistry; Heat Effect; Supporting Electrolyte; Zwitterion;
D O I：
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学科分类号：
摘要：
Heat effects of mixing of aqueous solutions of Cu(NO3)2 and L-valine were measured by the calorimetric method at 298.15 K and a ionic strength of 0.5–1.5 (KNO3). The standard heat effects of formation of the Cu(II) complexes with L-valine in an aqueous solution were obtained by the extrapolation to the zero ionic strength using the equation with one individual parameter. The standard thermodynamic characteristics of complex formation in the Cu2+-L-valine system were calculated.
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页码：693 / 696
页数：3
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