Palladium-containing composite nanomaterials based on polycaprolactam: Formation and structure

被引:0
|
作者
I. D. Akhmadov
N. E. Mel′nikova
A. Z. Babayeva
V. M. Akhmedov
机构
[1] National Academy of Sciences of Azerbaijan,Naghiyev Institute of Catalysis and Inorganic Chemistry
来源
关键词
palladium; polycaprolactam; nanocomposite; physico-chemical methods of analysis; heterogeneous catalysis;
D O I
暂无
中图分类号
学科分类号
摘要
Novel Pd(0) nanocomposites using polycaprolactam as a reducing and stabilizing matrix are synthesized. Data on the nanoparticle formation mechanism in a polycaprolactam matrix under the conditions of changing pH of the medium and reagent concentration ratios are obtained. The nanocomposite structure is studied by electron and infrared spectroscopy, X-ray diffraction analysis, atomic force and transmission electron microscopy. The size of metal-containing particles in the composite composition and their size distribution are determined. The obtained nanocomposites can serve as heterogeneous catalysts.
引用
收藏
页码:775 / 781
页数:6
相关论文
共 50 条
  • [21] ON THE MISCIBILITY OF SOME PALLADIUM-CONTAINING METALLIC GLASSES
    ELBORAGY, M
    ELLNER, M
    ZEITSCHRIFT FUR METALLKUNDE, 1993, 84 (08): : 580 - 583
  • [22] Direct synthesis of palladium-containing mesoporous carbon
    Hu, QY
    Pang, JB
    Jiang, N
    Hampsey, JE
    Lu, YF
    MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 81 (1-3) : 149 - 154
  • [23] A Palladium-Containing Polyoxotungstate with Anisotropic Proton Conductivity
    Jia, Lei
    Liu, Yi-Xin
    Li, Xin-Xiong
    Sun, Cai
    Zheng, Shou-Tian
    INORGANIC CHEMISTRY, 2024, 63 (31) : 14308 - 14312
  • [24] Palladium-Containing Catalysts Based on Functionalized Carbon Nanofibers for the Dehydrogenation of Methylcyclohexane
    G. B. Veselov
    D. M. Shivtsov
    S. D. Afonnikova
    I. V. Mishakov
    A. A. Vedyagin
    Kinetics and Catalysis, 2023, 64 : 925 - 927
  • [25] Specific features of the gravimetric determination of palladium in palladium-containing objects
    T. F. Vasekina
    I. V. Boryagina
    E. S. Pyatakhina
    N. V. Rovinskaya
    Inorganic Materials, 2014, 50 : 1371 - 1374
  • [26] Specific features of the gravimetric determination of palladium in palladium-containing objects
    Vasekina, T. F.
    Boryagina, I. V.
    Pyatakhina, E. S.
    Rovinskaya, N. V.
    INORGANIC MATERIALS, 2014, 50 (14) : 1371 - 1374
  • [27] ON STEREOSELECTIVITY OF CHIRAL PALLADIUM-CONTAINING MACROMOLECULAR CATALYSTS
    KRENTSEL, LB
    LITMANOVICH, AD
    PLATE, NA
    KARPEISKAYA, EI
    GODUNOVA, LF
    KLABUNOVSKII, EI
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1992, 34 (08): : 10 - 15
  • [28] PALLADIUM-CONTAINING AND PLATINUM-CONTAINING FREE-RADICALS
    MILAEVA, ER
    RUBEZHOV, AZ
    PROKOPHEV, AI
    MILAEV, AG
    OKHLOBYSTIN, OY
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 188 (03) : C43 - C45
  • [29] Spectroscopic Study of Palladium-containing Electrolytes.
    Bamburov, D.V.
    Vasin, B.D.
    Kazakov, A.S.
    Raspopin, S.P.
    Izvestiya Vysshikh Uchebnykh Zavedenij. Tsvetnaya Metallurgiya, 1983, (04): : 56 - 58
  • [30] Tetrachloromethane Hydrodechlorination over Palladium-Containing Nanodiamonds
    Kalmykov, P. A.
    Magdalinova, N. A.
    Gruzdev, M. S.
    Lysenok, A. A.
    Belkina, E. G.
    Klyuev, M. V.
    PETROLEUM CHEMISTRY, 2020, 60 (10) : 1148 - 1153