Enhanced enantioselectivity in halogen-bonding catalysis

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Victoria Richards

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[1] Communications Chemistry,

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Communications Chemistry | / 6卷

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摘要：

Chiral halogen-bonding catalysts have emerged as a new approach towards asymmetric catalysis, but enantioselectivities have thus far remained low. Now, fine-tuning the substrate–catalyst halogen–halogen interactions is shown to significantly enhance enantioselectivity for a model anion-binding-catalyzed dearomatization reaction.

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