Basicity and Nucleophilicity of Aryl-Containing N-Anions

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作者
V. M. Vlasov
I. A. Os'kina
机构
[1] Russian Academy of Sciences,Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division
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关键词
DMSO; Organic Chemistry; General Factor; Quantitative Study; Nucleophilic Substitution;
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摘要
New data on the basicity of N-centered anions in the gas phase and in DMSO solution are analyzed. The results of quantitative studies on the reactivity of N-anions in nucleophilic substitution are systematized, and general factors determining their nucleophilicity are discussed.
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页码:1705 / 1718
页数:13
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