Linear free energy relationships in SNAr reactions of aryl and diaryl N-anions with aryl halides

被引：3

作者：

Vlasov, VM ^{[1
]}

Os'kina, IA ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Vorozhtsov Inst Organ Chem, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2004年 / 74卷 / 04期

关键词：

D O I：

10.1023/B:RUGC.0000031864.05199.b2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A good correlation has been established between the Bronsted coefficients beta(Nuc) and beta(ox) for reactions of aryl-containing N-anions with various aryl halides. This correlation reflects the dependence of the internal barrier of aromatic nucleophilic substitution on the oxidation potentials of nucleophiles.

引用

页码：600 / 605

页数：6

共 50 条

[1] Linear Free Energy Relationships in SNAr Reactions of Aryl and Diaryl N-Anions with Aryl Halides
V. M. Vlasov
I. A. Os'kina
Russian Journal of General Chemistry, 2004, 74 : 600 - 605
[2] Basicity and Nucleophilicity of Aryl-Containing N-Anions
V. M. Vlasov
I. A. Os'kina
Russian Journal of Organic Chemistry, 2002, 38 : 1705 - 1718
[3] Basicity and nucleophilicity of aryl-containing N-anions
Vlasov, VM
Os'kina, IA
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2002, 38 (12) : 1705 - 1718
[4] REACTIONS OF ARYL HALIDES WITH TRIETHYLGERMYL ANIONS
MOCHIDA, K
MATSUSHIGE, N
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 229 (01) : 11 - 20
[5] C(aryl)-O bond formation from aryl methanesulfonates via consecutive deprotection and SNAr reactions with aryl halides in an ionic liquid
Xu, Hui
Chen, Yang
MOLECULES, 2007, 12 (04): : 861 - 867
[6] REACTIONS OF ARYL HALIDES WITH THIOLATE ANIONS IN PRESENCE OF CATALYTIC AMOUNTS OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM PREPARATION OF ARYL SULFIDES
KOSUGI, M
SHIMIZU, T
MIGITA, T
CHEMISTRY LETTERS, 1978, (01) : 13 - 14
[7] Transition-metal-free Coupling Reactions of Aryl Halides
Shirakawa, Eiji
Hayashi, Tamio
CHEMISTRY LETTERS, 2012, 41 (02) : 130 - 134
[8] CsOH/DMSO Promoted Reactions of Aryl Halides with Phenols: A Convenient Method for the Synthesis of Diaryl Ethers
Chen, Pingliang
Lu, Shijie
Hu, Xingen
Xu, Qing
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2014, 34 (01) : 112 - 117
[9] Synthesis of arylselenide ethers by photoinduced reactions of selenobenzamide, selenourea and selenocyanate anions with aryl halides
Bouchet, Lydia M.
Penenory, Alicia B.
Argueello, Juan E.
TETRAHEDRON LETTERS, 2011, 52 (09) : 969 - 972
[10] REACTIONS OF [MO(N2)2(DPPE)2] WITH ARYL HALIDES - A NEW SOURCE OF ARYL RADICALS
MINZONI, F
NARDELLI, M
PELIZZI, C
PREDIERI, G
CHIUSOLI, GP
GAZZETTA CHIMICA ITALIANA, 1984, 114 (5-6): : 221 - 224

← 1 2 3 4 5 →