Self-assembling in the systems МХ2–2-(7-bromo-2-oxo-5-phenyl-2,3-dihydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide–salicyl aldehyde (М = Сo, Ni, Zn; X = Cl, CH3COO)

被引：0
|
作者：
A. V. Pulya
I. I. Seifullina
L. S. Skorokhod
V. G. Vlasenko
A. L. Trigub
Ya. V. Zubavichus
S. I. Levchenkov
机构：
[1] I.I. Mechnikov Odessa National University,Research Institute of Physics
[2] Southern Federal University,Southern Scientific Center
[3] Russian Scientific Center “Kurchatov Institute”,undefined
[4] Russian Academy of Sciences,undefined
来源：
Russian Journal of General Chemistry | 2017年 / 87卷
关键词：
coordination compounds; cobalt(II); nickel(II); zinc(II); 2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1; -1,4-benzdiazepin-1-yl)acetohydrazide; salicylaldehyde;
D O I：
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学科分类号：
摘要：
By self-assembling in the systems MX2–2-(7-bromo-2-oxo-5-phenyl-2,3-dehydro-1Н-1,4-benzdiazepin-1-yl)acetohydrazide (Hydr)–salicyl aldehyde (HSal) (М = Co, Ni, Zn; X = Cl, CH3COO) the complexes of composition [Co(HydrSal)2], [Ni(HydrSal)2], [Zn(HydrHSal)Cl2], [Zn(HydrSal)(CH3COO)(H2O)] have been synthesized. The local atomic structure of the coordination unit was determined by the method of X-ray absorption spectroscopy. Thermal stability, electroconductivity, and magnetic susceptibility of the complexes have been studied.
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页码：86 / 91
页数：5
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