Reaction of rhodium trichloride with P-functionalized calix[4]resorcinols in various media

被引：0

作者：

E. V. Guseva

V. I. Morozov

D. T. Karimova

E. L. Gavrilova

A. A. Naumova

V. K. Polovnyak

E. A. Krasil’nikova

机构：

[1] Kazan State Technological University,Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center

[2] Russian Academy of Sciences,undefined

来源：

Russian Journal of General Chemistry | 2010年 / 80卷

关键词：

General Chemistry; Rhodium; Electron Absorption Spectrum; Resorcinol; Rhodium Complex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The features of the reaction of rhodium trichloride with calix[4]resorcinols modified with various types of phosphorus-containing groups in ethanol, ethanol-formate medium and acetone under an inert atmosphere were studied. Neutral complexes were isolated in the solid form, the solvent molecules were shown to be actively involved into the formation of the final reaction products. The compounds were characterized by IR, Raman, 31P NMR, ESR, X-ray photoelectron and electronic spectroscopy, and electric conductivity. The composition was confirmed by the data of elemental analysis, X-ray fluorescence analysis, and derivatography. Based on the analysis of the ESR spectrum, the electronic and geometric structures of the paramagnetic product isolated from the acetone medium was determined.

引用

页码：47 / 59

页数：12

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