Reaction of 2-perfluoroalkanoylcyclohexane-1,3-diones and 3-chloro-2-perfluoroalkanoylcyclohex-2-ene-1-ones with amines

被引：0
|
作者：
T. S. Khlebnikova
V. G. Isakova
F. A. Lakhvich
机构：
[1] National Academy of Sciences of Belarus,Institute of Bioorganic Chemistry
来源：
Russian Journal of Organic Chemistry | 2009年 / 45卷
关键词：
Navuk BSSR; Sethoxydim; Colorless Oily Substance; Tricarbonyl Compound; Enamino Derivative;
D O I：
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中图分类号：
学科分类号：
摘要：
Reactions of 2-perfluoroalkanoylcyclohexane-1,3-diones with primary and secondary amines involved acid cleavage of the substrate with formation of the corresponding 3-aminocyclohex-2-en-1-ones. Vinylogous nucleophilic substitution in 3-chloro-2-perfluoroalkanoylcyclohex-2-ene-1-ones with amines led to the formation of 3-amino-2-perfluoroalkanoylcyclohex-2-ene-1-ones.
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页码：993 / 1001
页数：8
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