Synthesis of glycidyl ethers derived from terpene α-amino oximes and β-substituted alcohols on their basis

被引：0
|
作者：
T. A. Shumilova
A. M. Agafontsev
A. V. Tkachev
机构：
[1] Novosibirsk State University,Department of Natural Sciences
[2] Siberian Branch of the Russian Academy of Sciences,N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
来源：
Russian Chemical Bulletin | 2015年 / 64卷
关键词：
glycidyl ethers; β-amino alcohols; microwave synthesis; nitrosochlorides; monoterpenes; 3-carene; α-pinene; limonene; α-amino oximes;
D O I：
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中图分类号：
学科分类号：
摘要：
3-Carene, α-pinene, and limonene α-(dimethylamino)oximes were converted to glycidyl ethers at the oxime hydroxyl. The compounds obtained were involved in the reactions with amines, imidazole, as well as with anions of these dimethylamino oximes. The glycidyl ether epoxide ring opening by amines under microwave irradiation conditions proceeds considerably faster than upon convection heating.
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页码：99 / 106
页数：7
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