Mercuration of Salts of 2- and 4-Methyl-substituted Heterocyclic Cations: A Quantum-Chemical Study

被引：0
|
作者：
E. V. Laskatelev
A. I. Moskalenko
V. I. Boev
机构：
[1] Lipetsk State Pedagogical University,
来源：
Russian Journal of General Chemistry | 2004年 / 74卷
关键词：
Mercury; Pyridinium; Structural Factor; Quinolinium; Main Trend;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The deprotonation energies (ΔHr) of salts of 2- and 4-methyl-substituted pyridinium, pyrylium, quinolinium, and indolinium salts were evaluated by AM1 calculations. These data allow prediction of the mercuration pathway in reactions of these compounds with mercury salts. The structural factors affecting ΔHr and the main trends in variation of the geometric and electronic structures of the compounds upon their deprotonation in the course of mercuration were analyzed.
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页码：266 / 270
页数：4
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