Mercury contamination of two e-waste recycling sites in Ghana: an investigation into mercury pollution at Dagomba Line (Kumasi) and Agbogbloshie (Accra)

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作者
Lydia Otoo Amponsah
Peter Borgen Sørensen
Marian Asantewah Nkansah
Katrin Vorkamp
Lily Lisa Yevugah
Godfred Darko
机构
[1] Kwame Nkrumah University of Science and Technology,Department of Chemistry, College of Science
[2] Aarhus University,Department of Bioscience
[3] Aarhus University,Department of Environmental Science
[4] Kwame Nkrumah University of Science and Technology,Department of Geomatic Engineering, College of Engineering
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Soil pollution; Human health risk; Anthropogenic activity; Urban topsoils; Geostatistical analysis;
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摘要
This study investigated mercury pollution at two e-waste recycling sites in Ghana—Dagomba Line in Kumasi and Agbogbloshie in Accra. A total of 129 soil samples taken at 100 m and 50 m resolutions, respectively, for Dagomba Line and Agbogbloshie, were analysed for mercury using a Zeeman atomic absorption spectrometry. Mercury concentrations from the recycling sites (ranging from 0.11 to 7.57 mg/kg Dagomba Line, and 0.01–4.36 mg/kg at Agbogbloshie) were significantly higher than that of the surrounding areas (0.01–0.17 mg/kg in Kumasi and 0.01–2.18 mg/kg in Accra) and unpolluted control sites (0.05 mg/kg in Kumasi and 0.02 mg/kg in Accra). The dismantling sites at both locations had the highest mercury concentrations. Furthermore, the concentrations were significantly higher at the Dagomba Line site in Kumasi than at Agbogbloshie, even though the Dagomba Line site is relatively recent. The mercury concentrations at both sites exceeded the pollution prevention and abatement level of 0.1 mg/kg. However, the estimated human health risk showed no potential human health effects. Moreover, the mercury concentrations in water and sediment (0.12–7.69 ng/L and 0.02–0.28 ng/L for Dagomba Line and Agbogbloshie, respectively) were below the US EPA standards. Findings from this study show that e-waste recycling can contaminate the topsoil with mercury, irrespective of the scale of the activity.
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页码:1723 / 1737
页数:14
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